Trioxane is the most important monomer for polyacetal(POM) synthesis, POM
production technology with trioxane as the copolymerization monomer takes 80% of
the total POM capacity in the world. It is usually synthesized by enriching 37%
formalin to about 65% and then by oxidation in presence of acid catalyst such as
sulfuric acid. The production consists of formalin enrichment, trioxane
synthesis, trioxane enrichment, extraction, light components stripping and heavy
components stripping.
In trioxane production, one of the biggest problem is that a large amount of
steam will be consumed by formalin enrichment and the treatment of diluted
formalin generated from formalin enrichment. To solve this problem, SL TECH
proposes to oxidize methylal into high concentration formalin(75%) directly
instead of synthesis plus enrichment., and meanwhile the formalin generated from
trioxane enrichment can be charged back to the methylal synthesis unit. In this
way, a closed circuit system is formed. Also for those manufacturers with
formalin as the only feedstock, SL TEC has the propriatary license to provide a
special falling film vaporizer to enrich formalin to 78%-80%, and enrich the
diluted formalin by-product by customized distillation.